Asymmetric Organocatalysis Using Chiral Amines
Background; Aldol reactions; Mannich reactions; Amination/Oxidation reactions; Michael reactions; Cycloaddition reactions; Alkylation reactions. PDF script (USA) [e]
Enantioselective organocatalysis
This article shows how enantioselective organocatalysis can represent a powerful, complementary paradigm to metal-catalysed enantiolselective synthesis in the preparation of single enantiomers of chiral drug molecules for screening and clinical trials [e]
Green Synthesis - 1
Principles of Green Chemistry/Synthesis; Catalytic Methods. PDF text (USA) [e]
Organocatalysis
Almost Everything You Wanted to Know, but Never Asked ... PDF text (USA) [e]
Organocatalysis
Organocatalysis uses small organic molecules predominantly composed of C, H, O, N, S and P to accelerate chemical reactions (CH) [e, d]
Chiral 2,2'-Bipyridine-Type N-Monoxides
... as Organocatalysts in the Enantioselective Allylation of Aldehydes with Allyltrichlorosilane. Article, organic-chemistry.org (CH) [e]
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Asymmetric catalysis represents still one of the major challenges in modern organic chemistry. Besides the well-established asymmetric metal-complex-catalysed syntheses and biocatalysis, the use of "pure" organic catalysts turned out to be an additional efficient tool for the synthesis of chiral building blocks. In this handbook, the experienced authors from academia and industry provide the first overview of the important use of such metal-free organic catalysts in organic chemistry. With its comprehensive description of numerous reaction types, e.g., nucleophilic substitution and addition reactions as well as cycloadditions and redox reactions, this book targets organic chemists working in industry and academia, and reserves a place in every laboratory. Wiley-VCH 2005.
In this reference leaders at the forefront of research provide an insight into one of the hottest topics in organic synthesis, focusing on the most important enantioselective reactions. Clearly structured, each entry begins with a concise introduction, including a mechanistic discussion of the reaction, followed by preparative guidelines for newcomers, such as carefully selected working procedures with critical notes for bench chemists, rules of thumb and tips and tricks. Wiley-VCH, 2007.
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