Nanotube ink: Desktop printing of carbon nanotube
patterns
Troy, N.Y. - Using an off-the-shelf inkjet printer,
a team of scientists has developed a simple technique for printing
patterns of carbon nanotubes on paper and plastic surfaces. The method,
which is described in the August 2006 issue of the journal Small,
could lead to a new process for manufacturing a wide range of
nanotube-based devices, from flexible electronics and conducting
fabrics to sensors for detecting chemical agents.
Carbon nanotubes have enticed researchers since
their discovery in 1991, offering an impressive combination of high
strength, low weight, and excellent conductivity. But most current
techniques to make nanotube-based devices require complex and
expensive equipment. "Our results suggest new alternatives for
fabricating nanotube patterns by simply printing the dissolved
particles on paper or plastic surfaces," said Robert Vajtai, a
researcher with the Rensselaer Nanotechnology Center at Rensselaer
Polytechnic Institute and corresponding author of the paper.
Electrically conductive image of Albert Einstein
printed on copier paper with carbon nanotube ink.
Vajtai and his colleagues at Rensselaer -
along with a group of researchers led by Krisztián Kordás and Géza
Tóth at the University of Oulu in Finland - have developed an approach
that uses a commercial inkjet printer to deposit nanotubes onto
various surfaces. They simply fill a conventional ink cartridge with a
solution of carbon nanotubes dissolved in water, and then the printer
produces a pattern just as if it was printing with normal ink. Because
nanotubes are good conductors, the resulting images also are able to
conduct electricity.
"Printed carbon nanotube structures could be useful
in many ways," Vajtai said. "Some potential applications based on
their electrical conductivity include flexible electronics for
displays, antennas, and batteries that can be integrated into paper or
cloth." Printing electronics on cloth could allow people to actually "wear"
the battery for their laptop computer or the entire electronic system
for their cell phone, according to Vajtai.
The technique could be used to print optical tags
on money and other paper items that need to be tracked, and it could
even lead to an electronic newspaper where the text can be switched
without changing the paper, he said. The researchers printed different
samples, some of which show sensitivity to the vapors of several
chemicals, which also could make them useful as gas sensors.
The approach is simple, versatile, and inexpensive,
which makes it superior to other methods for producing conductive
surfaces, according to Vajtai. "A great advantage of our process is
that the printed patterns do not require curing, which is known to be
a limiting factor for conventional conductive ink applications," he
said. "And since our ink is a simple water-based dispersion of
nanotubes, it is environmentally friendly and easy to handle and store."
Because the process uses off-the-shelf printers,
cartridges, and paper or plastic surfaces, the only real expense is
the cost of the nanotubes. For this experiment, the researchers made
their own multi-walled carbon nanotubes, which were then chemically
modified to allow them to dissolve in water. But similar nanotubes can
be purchased for as little as a tenth of the price of the more
expensive single-walled variety of carbon nanotubes, Vajtai said. And
the cost of nanotubes should continue to drop as commercial demand for
higher volumes grows.
The researchers plan to continue optimizing the
process to improve the quality of the nanotube ink and the
conductivity of the printed images. At present, the paper or plastic
must be run through the printer multiple times to get an electrically
conductive pattern, with the conductivity increasing after each
repetition. They also hope to experiment with different chemical
modifications to produce a diversity of ink "colors," each producing
surface patterns with different properties, Vajtai said.
Source
/ Further
information:
-
Publishing date: 31-Aug-2006
-
Krisztián Kordás, Tero Mustonen, Géza Tóth,
Heli Jantunen, Marja Lajunen, Caterina Soldano, Saikat Talapatra,
Swastik Kar, Robert Vajtai, Pulickel M. Ajayan -
Inkjet Printing of Electrically Conductive Patterns of Carbon
Nanotubes - Small, Volume 2, Issue 8-9, Pages 1021 - 1025,
DOI 10.1002/smll.200600061
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Several other Rensselaer researchers collaborated with Vajtai on
the project: Pulickel Ajayan, the Henry Burlage Professor of
Materials Science and Engineering; Swastik Kar, a postdoctoral
research associate in materials science and engineering; Saikat
Talapatra, a postdoctoral research associate with the Rensselaer
Nanotechnology Center; and Caterina Soldano, a doctoral student in
physics, applied physics, and astronomy. From the University of
Oulu, Tero Mustonen, Heli Jantunen, and Marja Lajunen also
contributed to the research.
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In September 2001,
the National Science Foundation selected Rensselaer as one of the
six original sites for a new Nanoscale Science and Engineering
Center (NSEC). As part of the U.S. National Nanotechnology
Initiative, the program is housed within the Rensselaer
Nanotechnology Center and forms a partnership between Rensselaer,
the University of Illinois at Urbana-Champaign, and Los Alamos
National Laboratory. The mission of Rensselaer's Center for
Directed Assembly of Nanostructures is to integrate research,
education, and technology dissemination, and to serve as a
national resource for fundamental knowledge in directed assembly
of nanostructures. The five other original NSECs are located at
Harvard University, Columbia University, Cornell University,
Northwestern University, and Rice University.
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Rensselaer Polytechnic Institute, founded in 1824, is the
nation's oldest technological university. The university offers
bachelor's, master's, and doctoral degrees in engineering, the
sciences, information technology, architecture, management, and
the humanities and social sciences. Institute programs serve
undergraduates, graduate students, and working professionals
around the world. Rensselaer faculty are known for pre-eminence in
research conducted in a wide range of fields, with particular
emphasis in biotechnology, nanotechnology, information technology,
and the media arts and technology. The Institute is well known for
its success in the transfer of technology from the laboratory to
the marketplace so that new discoveries and inventions benefit
human life, protect the environment, and strengthen economic
development.
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